• 专利附录
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    • 专利摘要:
    A high modulus (50) to at least three twisted (T1, T2, T3) textile cord having at least N strands (20a, 20b, 20c, 20d), N being greater than 1, twisted together in a final twist T3 and a final direction D2, each strand consisting of M pre-strands (10a, 10b, 10c), M being greater than 1, themselves twisted together according to an intermediate torsion T2 (T2a, T2b, T2c, T2d) and a direction intermediate D1 opposite D2, each pre-strand itself consisting of a yarn (5) which has been previously twisted on itself according to an initial twist T1 (T1a, T1b, T1c) and the direction D1, in which at least half of the N times M spun has an initial module in extension noted Mi which is greater than 2000 cN / tex. This textile cord is advantageously usable as a reinforcement in vehicle tires, in particular in the belt or in the carcass reinforcement of these tires.
    公开号:FR3029542A1
    申请号:FR1462105
    申请日:2014-12-09
    公开日:2016-06-10
    发明作者:Richard Cornille；Jeremy Guillaumain；Clerc Christophe Le；Augustin Bosquet
    申请人:Michelin Recherche et Technique SA Switzerland ；Compagnie Generale des Etablissements Michelin SCA；Michelin Recherche et Technique SA France；
    IPC主号:
    专利说明:

    [0001] FIELD OF THE INVENTION The present invention relates to textile reinforcing elements or "reinforcements" that can be used for reinforcing plastic articles or rubber articles such as tires for vehicles. It relates more particularly to cords or twists textile used in particular for the reinforcement of such tires. 2. STATE OF THE ART The textile is used as reinforcement since the origins of the tire.
    [0002] Textile cords, made from continuous textile fibers such as polyester, nylon, cellulose or aramid fibers, play an important role in tires, including high-performance tires approved for use at very high speeds. In order to meet the requirements of the tires, they must have a high tensile strength, a high extension modulus, good fatigue endurance and good adhesion to the rubber matrices or other polymers that they are likely to reinforce. . It will be recalled here simply that these twisted or cabled textiles, traditionally double twist (Ti, T2), are prepared by a twisting process in which: - during a first step, each yarn or fiber multifilamentary (in English "yarn") constitutive of the final cable is first individually twisted on itself (according to an initial twist Ti) in a given direction Dl (respectively S or Z direction), to form a strand (in English "Strand") in which the elementary filaments are imposed a helical deformation around the fiber axis (or axis of the strand); and then, during a second step, several strands, generally two, three or four in number, of identical or different natures in the case of so-called hybrid or composite cords, are then twisted together according to a final twist T2 (which may be be equal to or different from Ti) in the opposite direction D2 (respectively Z or S direction, according to a recognized nomenclature designating the orientation of the turns according to the transverse bar of an S or Z), to obtain the cable (English "card") or final assembly with several strands.
    [0003] P10-3474 3029542 - 2 - The role of the twisting is to adapt the properties of the material in order to create the transverse cohesion of the reinforcement, to increase its resistance in fatigue and also to improve the adhesion with the reinforced matrix.
    [0004] Such textile cords, their constructions and manufacturing processes are well known to those skilled in the art. They have been described in detail in a large number of documents, to mention only a few examples in the documents EP 021 485, EP 220 642, EP 225 391, EP 335 588, EP 467 585, US 3,419,060, US 3. 977,172, US 4,155,394, US 5,558,144, WO97 / 06294 or EP 848,767, or more recently WO2012 / 104279, WO2012 / 146612, WO2014 / 057082. To be able to reinforce rubber articles such as tires, the resistance to fatigue (endurance in extension, flexion, compression) of these textile cords is essential. It is known that, in general, for a given material, it is all the greater in that the twists used are important, but that in return, their tensile strength in extension (called toughness when it is reduced to weight unit) decreases inexorably when increases torsion, which of course is penalizing from the point of view of reinforcement.
    [0005] Also, designers of textile cords, such as tire manufacturers, are constantly looking for textile cords whose mechanical properties, particularly breaking strength and toughness, for a given material and twist, could be improved. 3. BRIEF DESCRIPTION OF THE INVENTION In the course of their research, the Applicants have precisely found a new high-modulus type of textile cord whose specific architecture and construction unexpectedly allow, for a given final twist, to improve not only strength-rupture and toughness properties, but also endurance properties in compression or flexion-compression. Thus, according to a first object, the present invention relates to a textile cord having at least triple twist (Ti, T2, T3), comprising at least N strands, N being greater than 1, twisted together in a torsion T3 and a direction D2 each strand consisting of M pre-strands, M being greater than 1, themselves twisted together in a twisting T2 and a direction D1 opposite to D2, each pre-strand itself consisting of a yarn which has been previously twisted on itself according to a torsion Ti and the direction Dl, in which at least half of the N times M spuns has an initial module in extension denoted Mi which is greater than 40 2000 cN / tex. The invention also relates to the use of such a textile cord as reinforcing element for articles or semi-finished products made of plastic or rubber such as pipes, belts, conveyor belts. , tires for vehicles, as well as these articles, semi-finished rubber products and tires themselves, both in the raw state (ie before firing or vulcanization) and in the cooked state (after cooking) The tires of the invention, in particular, may be intended for motor vehicles of the tourism, 4x4, SUV (Sport Utility Vehicles) type, but also for two-wheeled vehicles such as motorcycles, or for vehicles industrial vehicles selected from vans, "heavy goods vehicles" - ie, metros, buses, road transport vehicles (trucks, tractors, trailers), off-the-road vehicles -, agricultural or civil engineering machinery, other transport vehicles or handling.
    [0006] The textile cord of the invention is particularly intended for use in crown reinforcement (or belts) or in tire carcass reinforcement for the vehicles described above. The invention as well as its advantages will be readily understood in the light of the detailed description and the following exemplary embodiments, as well as FIGS. 1 to 7 relating to these examples which are diagrammatic (unless otherwise indicated, without respect for a scale specific): - in cross-section, a conventional (or spun) multifilament textile fiber, first in the initial state (5) that is to say devoid of torsion, then after a first twisting operation T1 in the direction D1, for forming a yarn twisted on itself or "pre-stranded" (10) (Fig. 1); - In cross section, the assembly of 3 yarns (10a, 10b, 10c) as above fulfilling the function of pre-strands (previously bent according to Tla, Tlb, Tlc in the same direction D1) which are assembled by a second twisting operation T2 always in the same direction D1, for forming a strand (20) for the cord according to the invention (Fig. 2); - In cross section, the assembly of 3 strands (20a, 20b, 20c) as above (previously twisted according to T2a, T2b, T2c in the same direction D1) which are assembled by a third T3 twist operation this time in the direction D2 opposed to the direction D1, for forming a final triple twisted textile cord (30) (T1, T2, T3) according to the invention (Fig. 3); - In cross section, the conventional assembly of 3 yarns (10a, 10b, 10c) as above filling this time directly the function of strands (all pre-twisted according to Tla, Tlb, Tlc in the direction D1) which are assembled by a second twisting operation T2 in the direction D2 opposite to the direction D1, for forming a textile cord according to the prior art (40) with a double twist (T 1, T 2) (FIG. 4); in cross-section, the assembly of 4 strands (20a, 20b, 20c, 20d) (previously twisted according to T2a, T2b, T2c, T2d in the same direction D1) which are joined by a third T3 torsion operation in the direction D2 opposite the direction D1, for forming a final textile cord (50) with a triple twist (Ti, T2, T3) according to the invention (FIG. - In cross section, another representation of the cord (50) above, less schematic than the previous one, illustrating that the final section of a textile cord 10 (whether or not it complies with the invention), once formed and under minimal tension, is closer in fact to a circular contour section, due to the high lateral plasticity provided by the multifilament nature of the starting material (Fig. 6); finally, in radial section (that is to say in a plane containing the axis of rotation of the tire), an example of a tire according to the invention incorporating a textile cord according to the invention (FIG. ). 4. DETAILED DESCRIPTION OF THE INVENTION In the present application, unless expressly indicated otherwise, all the percentages (%) indicated are percentages by weight. Any range of values designated by the expression "between a and b" represents the range of values from more than a to less than b (i.e., terminals a and b excluded) while any range of values denoted by "from a to b" means the range of values from a to b (i.e., including the strict limits a and b). The high-modulus textile cord or plied yarn of the invention is therefore (with reference to FIGS. 1 to 3, and 5 appended) a textile cord (30, 50) of very specific construction, whose essential characteristics include: at least one triple (i.e. three or more than three) torsion (Ti, T2, T3); at least N strands (20, 20a, 20b, 20c, 20d), N being greater than 1, which are twisted together in a final twist T3 and in the same final direction D2; each strand consisting of M pre-strands (10, 10a, 10b, 10c), M being greater than 1, themselves twisted together according to an intermediate torsion T2 (T2a, T2b, T2c, T2d) and an intermediate direction Dl opposite to D2; each pre-strand consisting of a yarn (5) which has been previously twisted on itself according to an initial twist Ti (Tla, Tb 1, Tic) and the initial direction Dl. By cord having at least one triple twist (i.e., three or more twists), one skilled in the art will immediately recognize that at least three consecutive untwisting (or twisting in inverse) are therefore necessary to "deconstruct" the cabled of the invention and "back" to the initial yarns constituting it, that is to say to find the yarns (multifilamentary fibers) starting in their initial state that is that is to say devoid of torsion. In other words, there are at least three (three or more) successive twisting operations to constitute the cable of the invention, and not two as is usually the case.
    [0007] Another essential feature is that at least half of the yarns constituting the cord has an initial modulus in extension denoted Mi which is greater than 2000 cN / tex. The structure of the textile cord of the invention as well as its manufacturing steps will now be described in detail.
    [0008] First of all, FIG. 1 schematizes, in cross-section, a conventional multifilament textile fiber (5), also called "spun" (in English "yarn"), in the initial state that is to say without torsion; as is well known, such a yarn is formed of a plurality of elementary filaments (50), typically several tens to several hundred, of very fine diameter generally less than 25 μm. After a twisting operation T1 (first twist) in a direction D1 (S or Z), the initial yarn (5) is transformed into a twisted yarn on itself called "pre-strand" (10). In this pre-strand, the elementary filaments are thus imposed a helical deformation around the fiber axis (or axis of the pre-strand). Then, as illustrated by way of example in FIG. 2, M pre-strands (for example here three in number: 10a, 10b, 10c) are then themselves twisted together, in the same direction D1 as before, according to an intermediate torsion T2 (second twist) for formation of a "strand" (20). Each pre-strand is characterized by a first specific torsion Ti (for example here, T la, T lb, Tic) which may be equal (in the general case, that is to say that here, for example, T the = Tlb = Tic) or different from one pre-strand to another. Finally, as shown diagrammatically in FIG. 3, N strands (for example here three in number: 20a, 35b, 20c) are themselves twisted together, in the direction D2 opposite to D1, according to a final twist T3 (third twist) for forming the final textile cord (30) according to the invention. Each strand is characterized by a second specific T2 twist (for example here, T2a, T2b, T2c) which may be equal (in the general case, that is to say that here we have for example T2a = T2b = T2c ) or different from one strand to another.
    [0009] The final textile cord (30) thus obtained, having N times M (here, for example new) pre-strand, is therefore characterized by (at least) a triple twist (Ti, T2, T3). ). The invention applies, of course, to cases where more than three successive twists, for example four in number (T 1, T 2, T 3, T 4) or five (T 1, T 2, T 3, T 4, T 5), would be applied to spun yarns (5). However, the invention is preferably implemented with only three successive operations of torsion (Ti, T2, T3), especially for reasons of cost.
    [0010] FIG. 4, as compared with FIG. 3, illustrates a conventional method of preparing double twisted textile cords. M pre-strands (for example here three in number, 10a, 10b, 10c) - in fact directly filling the function of strands - are twisted together in a (second) direction D2 opposite the (first) direction of torsion D1 , for direct formation of a double twist textile cord (40) (Ti, T2) according to the prior art.
    [0011] FIG. 5 schematizes, in cross-section, the assembly of 4 strands (20a, 20b, 20c, 20d) (previously twisted according to T2a, T2b, T2c, T2d in the same direction D1) which are assembled by a third operation of FIG. torsion T3 in the direction D2 opposite to the direction D1, for forming another example of a final cord (50) with triple torsion (Ti, T2, T3) according to the invention. Each strand is characterized by a second specific T2 twist (here, T2a, T2b, T2c, T2d) which may be equal to or different from one strand to another. As a reminder, FIG. 6 shows, again in cross-section, another representation of the preceding cord (50), less schematic than the previous one, recalling the well-known fact that the section of a textile cord, whether of Moreover, whether or not in accordance with the invention, once formed and under a minimum tension, it is closer in fact to a cylindrical structure with a substantially circular section, because of the high radial, lateral plasticity of the strands (20a). , 20b, 20c, 20d) and pre-strands (10a, 10b, 10c), provided by the multifilament nature of the fibers (spun) starting.
    [0012] In the present application, the term "textile" or "textile material", in a very general manner, any material made of a material other than metal, whether natural or synthetic, capable of being transformed into yarn, fiber or film by any suitable processing method. For example, without the following examples being limiting, a polymer spinning process such as, for example, melt spinning, solution spinning or gel spinning may be mentioned. Although materials of non-polymeric material (for example mineral material such as glass or non-polymeric organic material such as carbon) are included in the definition of textile material, the invention is preferably implemented with P10-3474 Polymeric materials, both of the thermoplastic type and of the non-thermoplastic type. By way of examples of high modulus textile yarns (here, by definition, having a Mi 5 modulus greater than 2000 cN / tex), mention may be made in particular of the high modulus "Lyocell" cellulosic fibers marketed by Hyosung, cellulosic fibers. high modulus cellulose formate or regenerated cellulose such as described in applications WO 85/05115 or WO 97/06294, polyvinyl alcohol fibers (abbreviated "PVA"), aramid fibers (aromatic polyamide), aromatic polyester fibers, polybenzazole fibers (abbreviated "PBO"), high density polyethylene ("HDPE") fibers such as "Dyneema" fibers marketed by the company DSM. According to a particularly preferred embodiment, the high modulus yarns of the textile cord of the invention are aramid yarns. By "aramid" is understood in a well-known manner a polymer consisting of linear macromolecules formed of aromatic groups linked to each other by amide bonds, at least 85% of which are directly bonded to two aromatic rings, and more particularly to poly fibers ( p-phenylene terephthalamide) (or PPTA), manufactured for a long time from optically anisotropic spinning compositions. Examples of such aramid spun yarns include, for example, the fibers marketed by DuPont under the name "Kevlar" by the company Teij in under the names "Twaron" or "Technora". Of course, the invention is applicable to cases where the textile cord of the invention is formed of several yarns of different materials to form a hybrid or composite cord, for example of which at least one yarn (i.e. say one or more) does not have a modulus Mi greater than 2000 cN / tex, of course at least half of the N times M spun with a Mi module greater than 2000 cN / tex. As particular examples of such hybrid cords include those based on yarns of at least aramid and cellulose, or aramid and polyketone.
    [0013] In the cable of the invention, N preferably varies in a range from 2 to 6, more preferably from 2 to 4. According to another preferred embodiment, M varies in a range from 2 to 6, more preferably from 2 to 6. According to another preferred embodiment, the total number of yarns (equal to N times M) is in a range from 4 to 25, more preferably from 4 to 16. In a manner well known to humans Twists can be measured and expressed in two different ways, either simply and in terms of the number of revolutions per meter (t / m), and this is more rigorous when it is desired to compare P10-3474 materials. 3029542 - 8 - nature (densities) and / or different titles, at helix angle of the filaments or equivalent in the form of a torsion factor K. The torsion factor K is related to the torsion T ( here, for example, respectively T1, T2 and T3) 5 according to the known relation e follows: K = (Twisting T) x [(Title / (1000.0] 1/2 in which the torsion T of the elementary filaments (constituting the pre-strand, strand or plied) 10 is expressed in revolutions per meter, the title is expressed in tex (weight in grams of 1000 meters of pre-strand, strand or twisted), and finally p is the density or density (in g / cm3) of the material constituting the pre-strand, strand or plied (for example about 1.50 g / cm 3 for cellulose, 1.44 g / cm 3 for aramid, 1.38 g / cm 3 for a polyester such as PET, 1.14 g / cm 3 for nylon); in the case of a hybrid cable, it is of course an average of the densities weighted by the respective titles of the constituent materials of the pre-strands, strands or twists. In the cable of the invention, preferably, the twist Ti expressed in revolutions per meter (t / m) is between 10 and 350, more preferably between 20 and 200. According to another preferred embodiment, each pre-strand presents a torsion coefficient K1 which is between 2 and 80, more preferably between 6 and 70. According to another preferred embodiment, the torsion T2 expressed in revolutions per meter is preferably between 25 and 470, more preferably between 25 and 470, more preferably and 400. According to another preferred embodiment, each strand has a torsion coefficient K2 which is between 10 and 150, more preferably between 20 and 130. According to another preferred embodiment, the torsion T3 expressed in turns by meter is preferably between 30 and 600, more preferably between 80 and 500. According to another preferred embodiment, the cable of the present invention a torsion coefficient K3 which is between 50 and 500, more preferably between 80 and 230. Preferably, T2 is greater than Ti (T1 and T2 being in particular expressed in t / m). According to another preferred mode, combined or not with the preceding one, T2 is lower than T3 (T2 and T3 being in particular expressed in t / m), T2 being more preferably between 0.2 and 0.95 and 35 times T3, in particular between 0.4 and 0.8 times T3. According to another preferred embodiment, the sum T1 + T2 is between 0.8 and 1.2 times T3, more preferably between 0.9 and 1.1 times T3 (T1, T2 and T3 being in particular expressed in t / m), T1 + T2 being in particular equal to T3.
    [0014] In the cable of the invention, preferably the majority, more preferably all of the N times M spun (in the initial state, that is to say without the Ti twist) present. a module Mi which is greater than 2000 cN / tex, more preferably greater than 2500 cN / tex. The initial module in extension Mi, or Young's modulus, is of course the module in longitudinal extension 5 that is to say along the axis of the yarn. More preferably, at least half, in particular the majority, of the spun N times M has a modulus Mi greater than 3000 cN / tex, more particularly greater than 3500 cN / tex. Even more preferably, it is the totality of the N times spun which has a modulus Mi greater than 3000 cN / tex, more particularly greater than 3500 cN / tex. All the properties (title, initial modulus of the yarns, breaking strength and toughness) given above are determined at 20 ° C on unbleached or glued cords (that is to say, unglued). say ready to use or extracts from the article they reinforce) that have been subjected to prior conditioning; "Prior conditioning" means the storage of cords (after drying) for at least 24 hours, before measurement, in a standard atmosphere according to the European standard DIN EN 20139 (temperature of 20 ± 2 ° C, hygrometry of 65 ± 2 %).
    [0015] The titre (or linear density) of the pre-strands, strands or cords is determined on at least three samples, each corresponding to a length of at least 5 m per weighing of this length; the title is given in tex (weight in grams of 1000 m of product - recall: 0, 111 tex equal to 1 denier).
    [0016] The mechanical properties in extension (toughness, initial modulus, elongation at break) are measured in a known manner using an "INSTRON" traction machine equipped with "4D" type clamping tongs (for lower breaking force). at 100 daN) or "4E" (for breaking strength at least equal to 100 daN), unless otherwise indicated in accordance with ISO 6892 of 1984. The tested samples are pulled to an initial length of 400 mm for the 4D forceps and 800 mm for 4E clamps, at a nominal speed of 200 mm / min, under a standard pretension of 0.5 cN / tex. All results given are an average of 10 measurements. When the properties are measured on yarns, the latter are known in a well-known manner a very low preliminary torsion, known as "protective torsion", corresponding to a helix angle of about 6 degrees, before positioning and pulling in the grippers. . The tenacity (force-fracture divided by the title) and the initial modulus in extension (or Young's modulus) are indicated in cN / tex or centinewton by tex (for recall, 1 cN / tex equal to 0.111 g / den (gram by denier)). The initial modulus is represented by the tangent at the origin 40 of the Force-Elongation curve, defined as the slope of the linear part of the P10-3474 -10- Force-Elongation curve which occurs just after a standard pretension of 0 , 5 cN / tex. The elongation at break is indicated in percentage. 5. EXEMPLARY EMBODIMENTS OF THE INVENTION The textile cord of the invention is advantageously usable for the reinforcement of tires of all types of vehicles, in particular motorcycles, passenger vehicles or industrial vehicles such as heavy vehicles, civil engineering, other transport or handling vehicles.
    [0017] By way of example, FIG. 7 very schematically shows (without respecting a specific scale) a radial section of a tire according to the invention, for example for a tourism type vehicle.
    [0018] This tire 100 comprises a crown 102 reinforced by a crown reinforcement 106, two sidewalls 103 and two beads 104, each of these beads being reinforced with a rod 105. The top 102 is surmounted by a tread, not shown. in this schematic figure. A carcass reinforcement 107 is wrapped around the two rods in each bead, the upturn 108 of this armature 107 being for example 20 disposed towards the outside of the tire 100 which is shown here mounted on its rim 109. The carcass reinforcement 107 is in a manner known per se consisting of at least one rubber ply reinforced by so-called "radial" textile cords, that is to say that these cords are arranged substantially parallel to one another and extend from one to the other. bead to the other so as to form an angle between 80 ° and 90 ° with the median circumferential plane (plane perpendicular to the axis of rotation of the tire which is located halfway between the two beads 104 and passes through the middle of the vertex frame 106). The belt 106 is for example constituted, in a manner known per se, by at least two layers of rubber called "working plies" or "triangulation plies", superimposed and crossed, reinforced with metal cables arranged substantially parallel to each other. the others and inclined relative to the median circumferential plane, these working plies may be associated or not with other plies and / or fabrics of rubber. These working plies have the primary function of giving the tire a high drift rigidity. The belt 106 further comprises in this example a rubber sheet called "shrink web" reinforced by so-called "circumferential" reinforcing son, that is to say that these reinforcing son are arranged substantially parallel to each other and extend substantially circumferentially around the tire so as to form an angle preferably within a range of 0 to 10 ° with the medial circumferential plane. These circumferential reinforcing son have the primary function, it is recalled, to resist the centrifugation of the top at high speed. For example, this tire 100 of the invention has the essential feature that at least the belt of its belt (106) and / or its carcass reinforcement (107) comprises a textile cord according to the invention. According to another example of a possible embodiment of the invention, it is for example the rods (105) which could consist, in whole or in part, of a textile cord according to the invention.
    [0019] The rubber compositions used for these webs are conventional compositions for calendering textile reinforcements, typically based on natural rubber or other diene elastomer, a reinforcing filler such as carbon black, a vulcanization system and the like. usual additives. The adhesion between the composite textile cord of the invention and the rubber layer which coats it is ensured, for example, by a conventional adhesive composition, for example an adhesive of the RFL type or equivalent adhesive. 5.1. Tensile Testing Due to its specific construction, the textile cord of the invention has significantly improved tensile properties, as demonstrated by the following exemplary embodiments. Five different tensile tests (Tests Nos. 1 to 5) were carried out with a total of 11 textile cords of different constructions, conforming or not according to the invention, based on either nylon yarns or yarns. high modulus Mi (in these examples aramid yarns). The nature of each example of cord ("T" for control, "C" for comparative and "I" for according to the invention), the material used ("N" for nylon, "A" for aramid), its 30 construction and its final properties are summarized in the attached Table 1. The starting yarns are of course commercially available, for example nylon sold by the company Kordsa under the name "T728", or by the company PHP under the names "Enka 140HRT or" Enka 444HRST ", for the aramid by the company 35 DuPont under the name "Kevlar" or by the company Teijin under the name "Twaron". As already mentioned, toughness is the breaking force reported in the title, it is expressed in cN / tex. The apparent toughness (in daN / mm 2) is also indicated, in this case the breaking force is referred to the apparent diameter denoted 0 which is measured according to the following method. P10-3474 3029542 -12- A device is used which, using a receiver composed of a collecting optical system, a photodiode and an amplifier, makes it possible to measure the shadow of an illuminated wire by a parallel light LASER beam with an accuracy of 0.1 micrometer. Such a device 5 is marketed for example by the company Z-Mike, under the reference "1210". The method consists in fixing on a motorized moving table, under a standard pretension of 0.5 cN / tex, a sample of the wire to be measured, having been pre-conditioned. Solidary of the moving table, the wire is moved perpendicularly to the shadow measurement system at a speed of 25 mm / s and orthogonally cuts the beam LASER. At least 200 measurements of shadows are made over a length of 420 mm of wire; the average of these drop shadow measurements represents the apparent diameter 0. For each test, breaking strength, toughness and apparent toughness were also indicated in relative values, the base 100 being used for the control cord of each of the five tests.
    [0020] Control cords (denoted "T" in Table 1) are all characterized by a conventional double-twist construction Ti, T2; the other wired (comparative non-compliant with the invention, or in accordance with the invention) are all characterized by an unconventional construction with triple torsion Ti, T2, T3. Only cords C8, C9 and C11 are in accordance with the invention and combine the triple twist characteristic and being of high modulus yarns (in these examples, aramid yarns). To help reading this table 1, it will be noted here that for example that the construction denoted by "N47 / - / 3/4" of the control cable C 1 means that this cord is a double twist cable (Ti, T2) which is simply the result of a twisting operation (T2, D2 or S) of 4 different strands which were each prepared beforehand by a reverse twist operation (Ti, Dl or Z) of 3 individual nylon (N) spun yarns of title 47 tex. The construction marked "N47 / 1/3/4" of the cord C2 means that this cord is a triple twist cord (Ti, T2, T3) which is derived from a final twist operation (T3, D2 or S) of 4 different strands which have each been prepared beforehand by an intermediate twisting operation (T2) in the opposite direction (D1 or Z) of 3 pre-strands, each of these 3 pre-strands consisting of 1 single nylon (N) spun yarn of title 47 tex which has been previously twisted on itself during a first twisting operation Ti in the same direction (D1 or Z) as for the pre-strands. The examples of control cords ("T") C1, C3, C5, C7 and C10 are all characterized by a double twist construction; they were manufactured by assembling 2, 3 or 4 strands according to a (second) final twist (T2) varying from 150 to 300 t / m depending on the case, corresponding to a torsion coefficient K2 ranging from 175 to 215 and a direction D2 (direction S). In a conventional manner, each of these strands had previously been manufactured by a (initial) initial twist (denoted Ti) of 150 to 300 rpm, depending on the case, of a yarn on itself. in the opposite direction Dl (Z direction).
    [0021] The 3 examples of C8, C9 and C11 cords (also denoted "I" and in bold in Table 1) are characterized by a triple twist construction Ti, T2, T3 (in these example, Z / Z / S); they were manufactured by assembling 3 or 4 strands in a final twist (denoted T3) of 150 or 300 t / m (K3 203 or 215) and a direction D2 (S direction). According to the invention, each of these strands had previously been manufactured by assembling 3 pre-strands according to a T2 twist (110, 180 or 240 t / m) and an opposite direction D1 (Z direction), each of these -brins having itself been prepared beforehand by a twist Ti (respectively 40, 120 or 60 t / m) of a yarn on itself, in the direction Dl (Z direction). As for the 3 comparative examples (denoted "C" in Table 1) of cords not in accordance with the invention C2, C4 and C6, they are all characterized by a triple twist construction Ti, T2, T3. Unlike the cords according to the invention, the constituent yarns of these cords were all nylon yarns and not high modulus yarns. It is important to note that all the textile cords of these examples are characterized, regardless of the material (nylon or aramid) and the title (47, 94, 140, 55 or 330 tex) of their yarns, by final torsional coefficients (respectively K2 or K3 depending on whether the cord has a double twist Ti, T2, or triple torsion Ti, T2, T3) which are very close, of average value equal to about 195 (ranging from 175 to 215).
    [0022] In the detailed reading of this table 1, firstly, for the tests 1 to 3, all the ducts with nylon yarns (Mi approx. 440 cN / tex), that the passage of the double twist (Cl , C3 and C5) at triple torsion (C2, C4 and C6) is not accompanied by any significant change in breaking force or other properties (0, strength, toughness).
    [0023] On the other hand, for the tests 4 and 5, carried out with high modulus yarns (aramid yarns), more precisely "Kevlar" yarns of 55 tex or 330 tex (Mi of 4000 cN / tex approximately), it is possible to observe that the passage of the double torsion construction (respectively C7 and C10) to the triple torsion construction (respectively C8 and C9 on the one hand, C11 on the other hand), all things being equal, is accompanied unexpectedly: - From an improvement of 6% (C9 wired) to 16% (C11 wired) of breaking strength and 8% (C9 wired) to 17% (C11 wired) of toughness, which is very significant for the skilled person; P10-3474 -14- - combined with a significant decrease in the apparent diameter 0 and title, clear indicators of better compactness of the cords according to the invention and ultimately the quality of these reinforcements, thanks to their very specific construction ; - all ultimately resulting in an increase ranging from 12% (wired C9) to 5 26% (wired C11) apparent toughness. In summary, the invention therefore makes it possible, for the same given final twist, to improve the properties of compactness, breaking strength and toughness of high modulus textile cords such as aramid cords. In addition and surprisingly, their new construction gives them endurance in compression or flexion-compression which is also significantly improved, as attested by the results of endurance tests that follow. 5.2. Endurance tests in compression ("Disc Fatigue Test") or in flexion-compression ("Shoe Shine Test") For textile cords intended in particular for reinforcing tire structures, fatigue resistance can be analyzed by subjecting these wired to various known laboratory tests, including the fatigue test known as the "belt test" sometimes called "Shoe Shine test", or the fatigue test called "Disc Fatigue Test" (see for example EP 20 848 767 , U.S. 2,595,069, US 4,902,774, ASTM D885-591 Revised 67T), tests in which pre-bonded textile cords are incorporated into a rubber article which is vulcanized. The principle of the "belt" test, first of all, is as follows: the belt comprises two layers of the cord to be tested, in a known rubber mixture of the type commonly used for reinforcing tires. The axis of each cord is oriented in the longitudinal direction of the belt and the cords are separated from the faces of the latter by a gum thickness of about 1 mm.
    [0024] This belt is then subjected to the following stresses: the belt is driven cyclically, using a crank-crank system, around a roller of a given diameter, so that each elementary portion of the belt The belt is subjected to a tension of 15 daN and undergo cycles of variation of curvature which make it pass from an infinite radius of curvature to a given radius of curvature and this during 190 000 cycles, at a frequency of 7 Hz. variation of curvature of the belt causes the cabled of the inner layer, the one closest to the roller, a given geometric compression rate according to the diameter of the selected roller. At the end of these stresses, the cords of the inner layer are peeled off and the residual breaking strength of the tired cords is measured. The "Disc Fatigue Test" is another test well known to those skilled in the art, it consists essentially of incorporating test cords into rubber blocks, then, after cooking, to fatigue the test specimens. of rubber thus formed in compression, between two rotating disks, a very large number of cycles (in the examples which follow, 600 000 5 cycles at 33 cycles / s). After fatigue, the cords are extracted from the test pieces and their residual breaking force is measured. The cords C1 to C4, and C7 not in accordance with the invention and the cords C8 and C9 according to the invention of the previous tests were submitted on the one hand to the "Disc Fatigue Test" with a maximum geometrical compression ratio of the sample of about 16% (angle of 3 ° between the two discs), on the other hand the "Shoe Shine test" with a geometric compression ratio of the cords of the inner layer of about 12% (roller of 20 °). mm). In both cases, the residual fracture forces (Fr) indicated in relative values in the appended Table 2 were measured on the cords extracted after fatigue. For both fatigue conditions, the base 100 was selected for the residual breaking force (Fr) measured on the dual twisted control cords ("T") Ti, T2. A value greater than 100 indicates a residual breaking force that is increased, hence an endurance that is improved over the corresponding control.
    [0025] From the detailed reading of this table 2, it should first be noted that, for tests 1 and 2 conducted with nylon yarns, the transition from double torsion (respectively C1 and C3) to triple torsion (respectively C2 and C4), and this regardless of the type of test (Disc Fatigue Test or Shoe Shine Test), a noticeable change considering the usual precision on these 25 types of tests, in any case not of any improvement , endurance in compression or flexion-compression. On the other hand, for the test 4, conducted with high modulus yarns, it is surprisingly found that the transition from the double twist construction (C7 wired) to the triple torsion construction (cabled C8 and C9), all things being equal. In addition, there is unexpectedly a very noticeable improvement (ranging from 20% to 62% depending on the case) in the residual tensile strength for each of the two fatigue tests. It should be noted in particular that in the case of the cable C9 according to the invention, in which T2 is between 0.4 and 0.8 times (in this case, here 0.6 times) T3, the endurance is still improved compared to cable C8 according to the invention for which T2 does not verify this relationship. In conclusion, thanks to the invention, it is now possible, for the same given final twist, to improve not only the properties of compactness, strength at break and toughness of aramid textile cords. , but still their endurance in compression or flexion-compression, thus further optimizing the architecture of the tires that these cords are 5 likely to strengthen. P10-3474 3029542 -17- 5 Table 1 Coefficient of Mechanical Properties Torsions t / m Force 0 Toughness N ° Ref. Nature Construction torsion Title Tenacity Cable Wired Test Apparent Apparent Breaking - T1 T2 - K1 K2 T1 T2 T3 K1 K2 K3 daN mm tex cN / tex daN / mm2 1 Cl T N47 / - / 3/4 0 250Z 250S 0 88 176 35.3 100 1.05 638 55 100 41 100 C2 C N47 / 1/3/4 100Z 150Z 250S 20 53 176 34.1 97 1.02 642 53 96 42 102 2 C3 T N94 / - / 2/3 0 260Z 260S 0 106 183 41.2 100 1.03 636 65 100 50 100 C4 C N94 / 1/2/3 100Z 160Z 260S 29 65 183 42.3 103 1.04 640 66 102 50 100 3 C5 T N140 / - / 2/2 0 250Z 250S 0 124 175 44.5 100 1.02 613 73 100 54 100 C6 C N140 / 1/2/2 100Z 150Z 250S 35 74 175 43.5 98 1.03 608 72 99 52 96 4 C7 T A55 / - / 3/4 0 300Z 300S 0 102 203 110.6 100 1.07 777 142 100 122 100 C8 I A55 / 1/3/4 60Z 240Z 300S 12 81 203 119.4 108 1.03 764 156 110 143 117 C9 I A55 / 1/3/4 120Z 180Z 300S 23 61 203 116.9 106 1.04 765 153 108 137 112 5 C10 T A330 / - / 3/3 0 150Z 150S 0 124 215 404, 2 100 2,48 3482 116 100 84 100 C11 I A330 / 1/3/3 40Z 110Z 150S 19 91 215 467.8 116 2.37 3428 136 117 106 126 P10-3474 3029542 -18- 5 Table 2 Ref. Nature Wired Construction Torsions t / m Coefficient of torsion Disc Fatigue Test Shoe Shine Test Wired Test of Cable - T1 T2 - K1 K2 Fr residual Fr residual T1 T2 T3 K1 K2 K3 1 Cl T N47 / - / 3/4 0 250Z 250S 0 88 176 100 100 C2 C N47 / 1/3/4 100Z 150Z 250S 20 53 176 95 97 2 C3 T N94 / - / 2/3 0 260Z 260S 0 106 183 100 100 C4 C N94 / 1/2/3 100Z 160Z 260S 29 65 183 97 99 4 C7 T A55 / - / 3/4 0 300Z 300S 0 102 203 100 100 C8 I A55 / 1/3/4 60Z 240Z 300S 12 81 203 120 136 C9 I A55 / 1/3/4 120Z 180Z 300S 23 61 203 125 162 P10-3474
    权利要求:
    Claims (21)
    [0001]
    REVENDICATIONS1. A textile cord (30, 50) of at least triple twist (Ti, T2, T3), having at least N strands (20, 20a, 20b, 20c, 20d), N being greater than 1, twisted together in a twist T3 and a direction D2, each strand consisting of M pre-strands (10, 10a, 10b, 10c), M being greater than 1, themselves twisted together according to a T2 twist (T2a, T2b, T2c, T2d) and a direction D1 opposite D2, each pre-strand itself consisting of a yarn (5) which has been previously twisted on itself in a twist Ti (Tla, T lb, T1c) and the direction Dl, in which at least half of the N times M yarns has an initial module in extension noted Mi which is greater than 2000 cN / tex.
    [0002]
    The cable of claim 1, wherein N varies in a range from 2 to 6, preferably from 2 to 4.
    [0003]
    The cable of any of claims 1 or 2, wherein M varies in a range from 2 to 6, preferably from 2 to 4.
    [0004]
    4. The cable of any one of claims 1 to 3, wherein the total number N times M of yarns is in a range from 4 to 25, preferably from 4 to 16.
    [0005]
    5. Wired according to any one of claims 1 to 4, wherein the twist Ti expressed in revolutions per meter is between 10 and 350, preferably between 20 and 200.
    [0006]
    The cable of any one of claims 1 to 5, wherein each pre-strand has a torsion coefficient K1 of between 2 and 80, preferably between 6 and 70.
    [0007]
    7. The cable of any one of claims 1 to 6, wherein the T2 twist expressed in revolutions per meter is between 25 and 470, preferably between 35 and 400.
    [0008]
    The cord according to any one of claims 1 to 7, wherein each strand has a torsion coefficient K2 which is between 10 and 150, preferably between 20 and 130.
    [0009]
    9. The cable of any one of claims 1 to 8, wherein the torsion T3 expressed in revolutions per meter is between 30 and 600, preferably between 80 and 500. P10-3474 3029542 - 20 -
    [0010]
    Wired according to any one of claims 1 to 9, having a torsion coefficient K3 which is between 50 and 500, preferably between 80 and 230.
    [0011]
    The cable of any one of claims 1 to 10, wherein T2 is greater than T1.
    [0012]
    The cable of any one of claims 1 to 11, wherein T3 is greater than T2. 10
    [0013]
    The cable of claim 12, wherein T2 is 0.2 to 0.95 times T3, preferably 0.4 to 0.8 times T3.
    [0014]
    14. A wired according to any one of claims 1 to 13, wherein the sum T1 + T2 is between 0.8 and 1.2 times T3, preferably between 0.9 and 1.1 times T3.
    [0015]
    The cable of claim 14, wherein the sum T1 + T2 is equal to T3.
    [0016]
    Wired according to any one of claims 1 to 15, wherein the majority, preferably all, of the spun N times has a Mi modulus greater than 2000 cN / tex, preferably greater than 2500 cN / tex.
    [0017]
    The cable of any one of claims 1 to 16, wherein at least half, preferably most, of the spun N times has a Mi modulus greater than 3000 cN / tex.
    [0018]
    18. Use of a cord according to any one of claims 1 to 17, for the reinforcement of an article or semi-finished product of plastic or rubber. 30
    [0019]
    19. Article or semi-finished product made of plastic or cable-reinforced rubber according to one of Claims 1 to 17.
    [0020]
    20. Use of a cord according to any one of claims 1 to 17 for the reinforcement of a tire. 35
    [0021]
    21. A tire reinforced with a cord according to any one of claims 1 to 17. P10-3474
    类似技术:
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    同族专利:
    公开号 | 公开日
    JP2018500471A|2018-01-11|
    EP3230504B1|2019-07-17|
    CN107002314A|2017-08-01|
    US10689780B2|2020-06-23|
    WO2016091812A1|2016-06-16|
    US20170327978A1|2017-11-16|
    FR3029542B1|2017-07-28|
    CN107002314B|2020-03-17|
    JP6778192B2|2020-10-28|
    EP3230504A1|2017-10-18|
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    法律状态:
    2015-12-21| PLFP| Fee payment|Year of fee payment: 2 |
    2016-06-10| PLSC| Search report ready|Effective date: 20160610 |
    2016-12-22| PLFP| Fee payment|Year of fee payment: 3 |
    2017-12-21| PLFP| Fee payment|Year of fee payment: 4 |
    2019-09-27| ST| Notification of lapse|Effective date: 20190906 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1462105A|FR3029542B1|2014-12-09|2014-12-09|TEXTILE CABLE HIGH MODULE AT AT LEAST TRIPLE TORSION|FR1462105A| FR3029542B1|2014-12-09|2014-12-09|TEXTILE CABLE HIGH MODULE AT AT LEAST TRIPLE TORSION|
    US15/532,808| US10689780B2|2014-12-09|2015-12-07|High modulus textile cord with an at least triple twist|
    PCT/EP2015/078841| WO2016091812A1|2014-12-09|2015-12-07|High modulus textile cord with an at least triple twist|
    EP15805193.8A| EP3230504B1|2014-12-09|2015-12-07|High modulus textile cord with an at least triple twist|
    CN201580067353.6A| CN107002314B|2014-12-09|2015-12-07|High modulus textile cord with at least three twists|
    JP2017530127A| JP6778192B2|2014-12-09|2015-12-07|High modulus textile cord with at least triple twist|
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